There are many options for hotels, in and around the area of the wedding location, the main largest town is Aberystwyth, a coastal town in Wales, that has many things to do and places to stay.
Options to fly into here, rent a car and drive over to Wales, or take a train to Aberystwyth many direct flights. The train would have a couple of changes. You can find a lot of this information on Trainline.com for routes, and also if you search into google train route from Heathrow to Aberystwyth many options are available. The train is roughly 5 hours and 50 mins.
Alexandra Road, Aberystwyth , Ceredigion, SY23 1LH
Main Station in the town centre, you can train from the airports.
Dublin Airport
Dublin, Ireland
(01) 944 0440
You are also able to fly in Dublin Ireland and take a Ferry over to Wales. It would then be a two hour drive up to Aberystwyth so I would recommend researching first. Get in touch if you need more help with this option.
This is further up north and a little closer, you most likely will have a stopover. The train is then around a 3 hour roughly direct train to Aberystwyth, from Birmingham International.